Author： Powell D.H. Gullidge P.M.N. Neilson G.W. Bellissent-Funel M.C.
Publisher： Taylor & Francis Ltd
ISSN： 1362-3028
Source： Molecular Physics, Vol.71, Iss.5, 1990-12, pp. : 1107-1116
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
A neutron-diffraction study has been carried out on solutions of 2 molal zinc trifluoromethanesulphonate (triflate) in heavy water and 4 molal zinc chloride in heavy water. The first-order isotopic-difference method was applied to Zn 2+ and the hydration of Zn 2+ was determined. Results for the zinc triflate solution show that Zn 2+ has a hydration number of 5·3(3), with water molecules situated at distances given by r ZnO = 2·09(2) Å and r ZnD = 2·69(2) Å. The results for the zinc chloride solution provide clear evidence for Zn 2+ …. Cl - complexation.
Related content
Access to resources
Recommend
Molecular Dynamics simulation of aqueous ZnCl2 solutions
By Harris D. J. Brodholt J. P. Harding J. H. Sherman D. M.
Molecular Physics, Vol. 99, Iss. 10, 2001-05 ,pp. :
DYNAMICS OF PROTONS IN WATER AND AQUEOUS ZnCl
Le Journal de Physique Colloques, Vol. 45, Iss. C7, 1984-09 ,pp. :
EXAFS-STUDY OF THE Zn
Le Journal de Physique Colloques, Vol. 47, Iss. C8, 1986-12 ,pp. :