Quasiclassical trajectory study of the Li + Cs 2 reaction

Author： Morais V.M.F.   Varandas A.J.C.  

Publisher： Taylor & Francis Ltd

ISSN： 1362-3028

Source： Molecular Physics, Vol.84, Iss.5, 1995-04, pp. : 957-969

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Abstract

We report quasiclassical trajectory calculations for the reaction Li + Cs 2 → LiCs + Li. The influence of the very pronounced mass differences of the colliding partners on the various dynamics attributes is investigated in detail. A remarkable linear dependence of the translational exothermicity as a function of the initial translational energy is observed, and rationalized using a hybrid statistical/stripping-spectator model.

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