Author： Dang Dong-Bin Fan Yan-Hua Bai Yan Jin Ya-Nan
Publisher： Taylor & Francis Ltd
ISSN： 1553-3174
Source： Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol.40, Iss.10, 2010-11, pp. : 748-753
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Abstract
A new bisupporting metal-oxygen cluster with bicapped pseudo-Keggin compound [CuII{Cl0.5Cl(phen)}]2 {[PMoV6MoVI6O40(VIVO)2][CuII(phen)2]2}·2H2O (phen = 1,10-phenathroline) has been synthesized by hydrothermal method and characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The polyoxoanion consists of a bicapped vanadium Keggin polyoxoanion and two {[Cu(phen)]2}2+ subunits producing bisupporting bicapped Keggin-polyoxometalate structure. The isolated dinuclear unit [CuII{Cl0.5Cl(phen)}2]+ acts as the countercation in title compound. In the crystal structure π - π stacking interactions, multiform C-H···O and O-H···O hydrogen bonds lead to a three-dimensional network.
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