Author： Dang Dong-Bin Guo Xiang-Yang Bai Yan Gao Hui Zhang Guo-Qiang
Publisher： Taylor & Francis Ltd
ISSN： 1553-3174
Source： Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol.40, Iss.3, 2010-03, pp. : 195-199
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
A new one-dimension Cd(II) coordination polymer [CdL2(NCS)2]n (L = (C5H4N)C(CH3) = N-N = C(CH3)(C5H4N)) has been synthesized and characterized by IR, UV, elemental analysis, TG technique and X-ray crystallography. Cd(II) atom has an distorted octahedral environment with a N6 donor set from four ligands and two NCS- anions, respectively. A pair of ligands bridge two adjacent Cd(II) centers to form one dimension chain structure containing bimetallic 22-membered macrometallacyclic rings. A 1D structure is held together with its neighboring ones via multiform hydrogen bonds to form a 3D supramolecular structure. The luminescent properties of the complex at room temperature were investigated.
Related content
By Bai Yan Gao Hui Dang Dong-Bin Hu Xue-Fu Guo Xiang-Yang
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol. 39, Iss. 9, 2009-11 ,pp. :
Access to resources
Recommend
By Li Jiaming He Kunhuan Jiang Yimin
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol. 43, Iss. 6, 2013-07 ,pp. :
By Shi J. -M. Zhang X. Xu H. -Y. Wu C. -J. Liu L. -D.
Journal of Coordination Chemistry, Vol. 60, Iss. 6, 2007-01 ,pp. :
By Wu Qiong Shi Quan Li Yang-Guang Wang En-Bo
Journal of Coordination Chemistry, Vol. 61, Iss. 19, 2008-01 ,pp. :