Synthesis, Characterization, Crystal Structure, Thermal Behavior, and Biological Activity of a New Heterotrinuclear Complex: [(NiL(NCS)(H2O))2Cd(DMF)2]

Author： Yardan Alper   Karahan Ahmet   Burcu Arslan N.   Hopa Cigdem   Gokmen Mukadderat   Kazak Canan   Kurtaran Raif  

Publisher： Taylor & Francis Ltd

E-ISSN： 1553-3182|45|8|1224-1233

ISSN： 1553-3174

Source： Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol.45, Iss.8, 2015-08, pp. : 1224-1233

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Abstract

A new trinuclear heterometallic nickel(II)-cadmium(II)-nickel(II) complex, [(NiL(NCS)(H2O))2Cd(DMF)2] (DMF: dimethylformamide) (1), has been synthesized by using NiL as the so-called metallo ligand where H2L = N,N′-bis(salicylidene)-1,3-diaminopropane, cadmium nitrate, and amonium thiocyanate. The title complex was characterized by various methods including elemental analyses, IR, 1H-NMR, 13C-NMR, TG-DTA, and X-ray diffraction techniques. The complex crystallizes in monoclinic space group P21/c, with unit cell dimensions a = 10.6217(3), b = 13.3487(4), c = 16.0043(4) Å, β = 93.823(2)°. The complex was screened for antimicrobial activities by the disc diffusion using DMF as solvent. The minimum inhibitory concentration values were calculated.

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