Publisher: John Wiley & Sons Inc
E-ISSN: 1521-3749|641|10|1706-1710
ISSN: 0044-2313
Source: ZAAC-JOURNAL OF INORGANIC AND GENERAL CHEMISTRY (ELECTRONIC), Vol.641, Iss.10, 2015-08, pp. : 1706-1710
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
AbstractThe self‐assembly reactions of transition metal ions and 1,3,5‐benzenetricarboxylic acid (H3btc) in the presence of auxiliary aromatic bidentate ligands 1,10‐phenanthroline (1,10‐phen) or 4,4′‐bipyridine‐N,N′‐dioxide (4,4′‐bpdo) have isolated four coordination polymers [Co18(btc)10(H2O)6(OH)6(1,10‐phen)6]·14H2O·3DMF (1) and [M3(btc)2(H2O)4(4,4′‐bpdo)]·2H2O·2DMF [M = Co (2), Mn (3), Ni (4)]. Single‐crystal X‐ray diffraction analysis revealed that the M3 clusters in the structure of 1–4 are connected by hydroxyl group oxygen atoms (or oxygen atoms from 4,4′‐bpdo ligands) and carboxyl groups to generate a three‐dimensional framework. The network of final assemblies can be adjusted by varying the type of auxiliary ligands (1,10‐phen, 4,4′‐bpdo). In addition, the gas adsorption properties of 2 are also investigated.
Related content
ZAAC-JOURNAL OF INORGANIC AND GENERAL CHEMISTRY (ELECTRONIC), Vol. 641, Iss. 5, 2015-04 ,pp. :
ZAAC-JOURNAL OF INORGANIC AND GENERAL CHEMISTRY (ELECTRONIC), Vol. 641, Iss. 8‐9, 2015-07 ,pp. :
By Sarma Rupam Chowdhury Pradip Bikkina Chaitanya Gumma Sasidhar Baruah Jubaraj
Journal of Chemical Crystallography, Vol. 40, Iss. 10, 2010-10 ,pp. :
ZAAC-JOURNAL OF INORGANIC AND GENERAL CHEMISTRY (ELECTRONIC), Vol. 641, Iss. 5, 2015-04 ,pp. :