Synthesis and Characterization of Bis(2‐iminopyrrolyl) Iron(II) Complexes by N–H Bond Activation

Publisher: John Wiley & Sons Inc

E-ISSN: 1521-3749|44-2313|11|1959-1963

ISSN: 0044-2313

Source: ZAAC-JOURNAL OF INORGANIC AND GENERAL CHEMISTRY (ELECTRONIC), Vol.44-2313, Iss.11, 2015-09, pp. : 1959-1963

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Abstract

Abstract The reactions of 2‐iminopyrroles 1–3 with Fe(PMe3)4 afforded the N–H activated bis(2‐iminopyrrolyl) iron(II) complexes 4–6. The structures of compounds 4–6 were determined by single‐crystal X‐ray diffraction. The formation mechanism of complexes 4–6 was discussed.