Oxidative Addition of Carbon–Carbon Bonds to Gold

Publisher： John Wiley & Sons Inc

E-ISSN： 1521-3757|127|17|5325-5329

ISSN： 0044-8249

Source： ANGEWANDTE CHEMIE, Vol.127, Iss.17, 2015-04, pp. : 5325-5329

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

AbstractThe oxidative addition of strained CC bonds (biphenylene, benzocyclobutenone) to DPCb (diphosphino‐carborane) gold(I) complexes is reported. The resulting cationic organogold(III) complexes have been isolated and fully characterized. Experimental conditions can be adjusted to obtain selectively acyl gold(III) complexes resulting from oxidative addition of either the C(aryl)C(O) or C(alkyl)C(O) bond of benzocyclobutenone. DFT calculations provide mechanistic insight into this unprecedented transformation.

Related content

Oxidative Addition of Carbon–Carbon Bonds to Gold

By  

ANGEWANDTE CHEMIE INTERNATIONAL EDITION, Vol. 54, Iss. 17, 2015-04 ,pp. : 5236-5240 (5)

John Wiley & Sons Inc

Access to resources Recommend Favorite

Enantioselective Hydroalkynylation of Non‐Polar Carbon‐Carbon Double Bonds: Iridium‐Catalyzed Asymmetric Addition Reaction of Terminal Alkyne CH Bonds to Substituted Norbornadienes

By  

ADVANCED SYNTHESIS & CATALYSIS, Vol. 357, Iss. 10, 2015-07 ,pp. : 2345-2350 (6)

John Wiley & Sons Inc

Access to resources Recommend Favorite

Direct Evidence for Intermolecular Oxidative Addition of σ(SiSi) Bonds to Gold

By  

ANGEWANDTE CHEMIE, Vol. 126, Iss. 3, 2014-01 ,pp. : 766-770 (5)

John Wiley & Sons Inc

Access to resources Recommend Favorite

Direct Evidence for Intermolecular Oxidative Addition of σ(SiSi) Bonds to Gold

By  

ANGEWANDTE CHEMIE INTERNATIONAL EDITION, Vol. 53, Iss. 3, 2014-01 ,pp. : 747-751 (5)

John Wiley & Sons Inc

Access to resources Recommend Favorite

Remarkable diversity of carbon–carbon bonds: structures and properties of fullerenes, carbon nanotubes, and graphene

By Dinadayalane T.   Leszczynski Jerzy  

Structural Chemistry, Vol. 21, Iss. 6, 2010-12 ,pp. : 1155-1169 (15)

Springer Publishing Company

Access to resources Recommend Favorite