Concise Syntheses of Insect Pheromones Using Z‐Selective Cross Metathesis

Publisher： John Wiley & Sons Inc

E-ISSN： 1521-3757|125|1|328-332

ISSN： 0044-8249

Source： ANGEWANDTE CHEMIE, Vol.125, Iss.1, 2013-01, pp. : 328-332

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Abstract

Sehr kurze Syntheserouten zu neun Pheromonen mit cis‐Olefingruppen und verschiedensten Funktionalitäten wie unkonjugierten (E,Z)‐Dienen werden vorgestellt (siehe Schema). Zum Einsatz kam eine Ruthenium‐basierte Z‐selektive Kreuzmetathese. Die synthetisierten Lepidopteran‐Pheromone werden in großen Mengen in der Schädlingsbekämpfung genutzt.

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