“(Diphosphine)Nickel”‐Catalyzed Negishi Cross‐Coupling: An Experimental and Theoretical Study

Publisher： John Wiley & Sons Inc

E-ISSN： 1521-3765|21|21|7690-7694

ISSN： 0947-6539

Source： CHEMISTRY - A EUROPEAN JOURNAL, Vol.21, Iss.21, 2015-05, pp. : 7690-7694

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

AbstractThe use of a strongly donating “(bis‐dialkylphosphine)Ni” fragment promotes the catalytic coupling of a large range of ArCl and ArZnCl derivatives under mild conditions. Stoichiometric mechanistic investigations and DFT calculations prove that a Ni0/NiII cycle is operative in this system.

Related content

Cobalt‐Catalyzed Negishi Cross‐Coupling Reactions of (Hetero)Arylzinc Reagents with Primary and Secondary Alkyl Bromides and Iodides

By  

ANGEWANDTE CHEMIE INTERNATIONAL EDITION, Vol. 54, Iss. 15, 2015-04 ,pp. : 4478-4481 (4)

John Wiley & Sons Inc

Access to resources Recommend Favorite

Frontispiece: Cobalt‐Catalyzed Enantioselective Negishi Cross‐Coupling of Racemic α‐Bromo Esters with Arylzincs

By  

CHEMISTRY - A EUROPEAN JOURNAL, Vol. 24, Iss. 9, 2018-02 ,pp. : n/a-n/a (NaN)

John Wiley & Sons Inc

Access to resources Recommend Favorite

Cobalt‐Catalyzed Enantioselective Negishi Cross‐Coupling of Racemic α‐Bromo Esters with Arylzincs

By  

CHEMISTRY - A EUROPEAN JOURNAL, Vol. 24, Iss. 9, 2018-02 ,pp. : 2059-2064 (6)

John Wiley & Sons Inc

Access to resources Recommend Favorite

Dialkyl Ether Formation by Nickel‐Catalyzed Cross‐Coupling of Acetals and Aryl Iodides

By  

ANGEWANDTE CHEMIE, Vol. 127, Iss. 34, 2015-08 ,pp. : 10014-10018 (5)

John Wiley & Sons Inc

Access to resources Recommend Favorite

Dialkyl Ether Formation by Nickel‐Catalyzed Cross‐Coupling of Acetals and Aryl Iodides

By  

ANGEWANDTE CHEMIE INTERNATIONAL EDITION, Vol. 54, Iss. 34, 2015-08 ,pp. : 9876-9880 (5)

John Wiley & Sons Inc

Access to resources Recommend Favorite