Publisher： John Wiley & Sons Inc
E-ISSN： 1521-3765|21|23|8394-8398
ISSN： 0947-6539
Source： CHEMISTRY - A EUROPEAN JOURNAL, Vol.21, Iss.23, 2015-06, pp. : 8394-8398
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
AbstractThe catalytic CH addition of pyridines to allenes has been achieved for the first time by using a half‐sandwich scandium catalyst, thus constituting a straightforward and atom‐economical route for the synthesis of alkenylated pyridine derivatives. The reaction proceeded regio‐ and stereoselectively, affording a new family of alkenylated pyridine compounds which are otherwise difficult to synthesize. A cationic Sc‐η2‐pyridyl species was isolated and confirmed to be a key catalyst species in this transformation.
Related content
Access to resources
Recommend
Potassium Amide‐Catalyzed Benzylic C−H Bond Addition of Alkylpyridines to Styrenes
ANGEWANDTE CHEMIE, Vol. 130, Iss. 6, 2018-02 ,pp. :
ZAAC-JOURNAL OF INORGANIC AND GENERAL CHEMISTRY (ELECTRONIC), Vol. 641, Iss. 12‐13, 2015-10 ,pp. :
ZAAC-JOURNAL OF INORGANIC AND GENERAL CHEMISTRY (ELECTRONIC), Vol. 44-2313, Iss. 12‐13, 2015-10 ,pp. :