Publisher： John Wiley & Sons Inc
E-ISSN： 1521-3773|54|19|5688-5692
ISSN： 1433-7851
Source： ANGEWANDTE CHEMIE INTERNATIONAL EDITION, Vol.54, Iss.19, 2015-05, pp. : 5688-5692
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Abstract
AbstractThe direct C(sp2)C(sp3) cross‐coupling of diaryl zinc reagents with benzylic, primary, secondary, and tertiary alkyl halides proceeded in the absence of coordinating ethereal solvents at ambient temperature without the addition of a catalyst. The C(sp2)C(sp3) cross‐coupling showed excellent functional‐group tolerance, and products were isolated in high yields, generally without the requirement for purification by chromatography. This process represents an expedient, operationally simple method for the construction of new C(sp2)C(sp3) bonds.
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