Publisher： John Wiley & Sons Inc
E-ISSN： 1521-3757|127|20|6110-6113
ISSN： 0044-8249
Source： ANGEWANDTE CHEMIE, Vol.127, Iss.20, 2015-05, pp. : 6110-6113
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Abstract
AbstractThe first organocatalytic enantioselective CH alkenylation and arylation reactions of N‐carbamoyl tetrahydropyridines and tetrahydro‐β‐carbolines (THCs) are described. The metal‐free processes represent an efficient and straightforward approach to a variety of structurally and electronically diverse α‐substituted tetrahydropyridines and THCs in good yields with excellent regio‐ and enantioselectivities. Preliminary control experiments provide important insights into the reaction mechanism.
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