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(Dihydroxyglyoxime‐κ2N,N′)bis(1,10‐phenanthroline‐κ2N,N′)manganese(II) dinitrate dihydrate

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|63|8|m2198-m2199

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.63, Iss.8, 2007-08, pp. : m2198-m2199

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Abstract

In the cation of the title compound, [Mn(C12H8N2)2(C2H4N2O4)](NO3)2·2H2O, the Mn atom has a distorted octahedral coordination formed by six N atoms from one dihydroxyglyoxime and two 1,10‐phenanthroline ligands. In the crystal structure, the components are linked into a three‐dimensional framework by O—H...O, C—H...O, C—H...N and O—H...N hydrogen bonds and π–π stacking interactions, with a centroid–centroid distance of 3.580 (2) Å (symmetry code: 1 − x, 2 − y, −z).