Publisher： John Wiley & Sons Inc
E-ISSN： 1600-5368|60|12|m1863-m1865
ISSN： 1600-5368
Source： Acta Crystallographica Section E, Vol.60, Iss.12, 2004-12, pp. : m1863-m1865
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Abstract
The title complex, [Ag2(C7H4ClO2)2(C5H6N2)2]·H2O, lies about an inversion center, with the water molecule on a twofold rotation axis, and the AgI atom is three‐coordinated by two O atoms from two different but symmetry‐related 4‐chlorobenzoate anions and one N atom from one 2‐aminopyridine ligand. The 4‐chlorobenzoate anion acts as a bidentate ligand, bridging two inversion‐related Ag atoms of the complex and forming a dimer. In the crystal structure, the molecules are linked through intramolecular and intermolecular N—H⋯O and O—H⋯O hydrogen bonds, forming two‐dimensional layers parallel to the bc plane.
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