Publisher： John Wiley & Sons Inc
E-ISSN： 1521-3757|127|34|10114-10117
ISSN： 0044-8249
Source： ANGEWANDTE CHEMIE, Vol.127, Iss.34, 2015-08, pp. : 10114-10117
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Abstract
AbstractControl of boronic acid speciation is presented as a strategy to achieve nucleophile chemoselectivity in the Suzuki–Miyaura reaction. Combined with simultaneous control of oxidative addition and transmetalation, this enables chemoselective formation of two CC bonds in a single operation, providing a method for the rapid preparation of highly functionalized carbogenic frameworks.
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