Publisher： John Wiley & Sons Inc
E-ISSN： 1521-3757|127|35|10358-10362
ISSN： 0044-8249
Source： ANGEWANDTE CHEMIE, Vol.127, Iss.35, 2015-08, pp. : 10358-10362
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
AbstractA highly efficient and versatile chemical cycle has been developed for the production of isocyanates through the molecular fixation of N2, CO2 and R3ECl (E=C, Si, and Ge). Key steps include a ‘one‐pot’ photolytic NN bond cleavage of a Group 6 dinuclear dinitrogen complex with in situ trapping by R3ECl to provide a metal terminal imido complex that can engage in simultaneous nitrene‐group transfer and oxygen‐atom transfer to generate an intermediate metal terminal oxo complex with release of the isocyanate product. Reaction of the oxo complex with additional equivalents of R3ECl regenerates a metal dichloride that is the precursor for dinuclear dinitrogen starting material.
Related content
Access to resources
Recommend
International Journal of Mathematical Education in Science and Technology, Vol. 30, Iss. 5, 1999-09 ,pp. :