Publisher： John Wiley & Sons Inc
E-ISSN： 2053-2296|71|9|759-762
ISSN： 0108-2701
Source： ACTA CRYSTALLOGRAPHICA SECTION C (ELECTRONIC), Vol.71, Iss.9, 2015-09, pp. : 759-762
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Abstract
The coordination polymer catena‐poly[[(dimethylformamide‐κO)[μ3‐5‐(1,3‐dioxo‐4,5,6,7‐tetraphenylisoindolin‐2‐yl)isophthalato‐κ4O1,O1′:O3:O3′](methanol‐κO)manganese(III)] dimethylformamide monosolvate], {[Mn(C40H23NO6)(CH3OH)(C3H7NO)]·C3H7NO}n, has been synthesized from the reaction of 5‐(1,3‐dioxo‐4,5,6,7‐tetraphenylisoindolin‐2‐yl)isophthalic acid and manganese(II) acetate tetrahydrate in a glass tube at room temperature by solvent diffusion. The MnII centre is hexacoordinated by two O atoms from one chelating carboxylate group, by two O atoms from two monodentate carboxylate groups and by one O atom each from a methanol and a dimethylformamide (DMF) ligand. The single‐crystal structure crystallizes in the triclinic space group P. Moreover, the coordination polymer shows one‐dimensional 2‐connected {0} uninodal chain networks, and free DMF molecules are connected to the chains by O—H...O hydrogen bonds. The thermogravimetric and photoluminescent properties of the compound have also been investigated.
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