2,3,4,5,6‐Pentafluoroaniline

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|63|6|o2954-o2954

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.63, Iss.6, 2007-06, pp. : o2954-o2954

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

In the title compound, C6H2F5N, the N atom of the amino group deviates by 0.19 (2) Å from the plane of its bonded atoms and thus has slightly pyramidal sp2 hybridization. The crystal packing is governed largely by N—H...F interactions and interaction of F atoms with the perfluorophenyl ring (C—F...πF = 3.21 and 3.25 Å). Intermolecular N—H...F hydrogen bonds link molecules into polar sheets parallel to the (100) plane.