Publisher： John Wiley & Sons Inc
E-ISSN： 1521-3757|127|51|15755-15759
ISSN： 0044-8249
Source： ANGEWANDTE CHEMIE, Vol.127, Iss.51, 2015-12, pp. : 15755-15759
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Abstract
AbstractAn efficient and selective Rh‐catalyzed direct CH functionalization reaction of enol phosphates was developed. The method is applicable to a variety of coupling partners, including activated alkenes, alkynes, and allenes, and leads to the formation of various valuable alkenylated and hydroalkenylated enol phosphates through the action of the phosphate directing group. The versatility and utility of the coupling products were demonstrated through further transformations into synthetically useful building blocks.
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