Redetermination of a cyclic triphosphenium hexachlorostannate salt at 173 K

E-ISSN： 1600-5368|62|6|m1235-m1236

ISSN： 1600-5368

Source： Acta Crystallographica Section E, Vol.62, Iss.6, 2006-06, pp. : m1235-m1236

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Abstract

At 173 K, the structure of the cyclic `triphosphenium' salt, bis[1,1,3,3‐tetraphenyl‐1,3,2‐triphospholenylium] hexachlorostannate(IV) dichloromethane solvate, (C₂₆H₂₄P₃)₂[SnCl₆]·2CH₂Cl₂, contains one cation, one solvent molecule and half of a centrosymmetric hexachlorostannate dianion in the asymmetric unit. There are no unusually short anion–cation distances and the structures of the component ions are comparable to those that have been reported previously.

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