(2,2′‐Bipyridine)(4‐bromo‐2‐formyl­phenolato)copper(II) perchlorate

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|62|6|m1225-m1226

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.62, Iss.6, 2006-06, pp. : m1225-m1226

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Abstract

The title compound, [Cu(C7H4BrO2)(C10H8N2)]ClO4, has been prepared by the reaction of 5‐bromo­salicylaldehyde and 2,2′‐bipyridine with Cu{ClO4)·6H2O. The two ligands coordinate the central Cu atom through two N [Cu—N = 1.981 (6) and 1.984 (7) Å] and two O [Cu—O = 1.888 (5) and 1.949 (6) Å] atoms. The coordination is completed by a perchlorate O atom, with a Cu—O distance of 2.533 (12) Å. The crystal packing is stabilized by weak Cu⋯O inter­actions and van der Waals forces.