Aquabis(1,10‐phenanthroline‐κ2N,N′)[2,4,6‐tris(4‐sulfonatophenylamino)‐1,3,5‐triazin‐1‐ium‐κO]nickel(II) dihydrate

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|63|8|m2119-m2119

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.63, Iss.8, 2007-08, pp. : m2119-m2119

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Abstract

In the title complex, [Ni(C21H16N6O9S3)(C12H8N2)2(H2O)]·2H2O or [Ni(HTST)(phen)2(H2O)]·2H2O, where H3TST is 2,4,6‐tris(4‐sulfophenylamino)‐1,3,5‐triazine and phen is phenanthroline, the NiII ion is in a distorted octahedral coordination environment defined by four N atoms from two phen ligands, one O atom from an aqua ligand and one O atom from the SO3 group of an HTST ligand. In the crystal structure, intermolecular N—H...O and O—H...O hydrogen bonds connect molecules to form a two‐dimensional network.