7‐Acetyl‐12‐methoxy­horminone from Jamaican Hyptis verticillata (Labiatae)

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|62|1|o306-o308

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.62, Iss.1, 2006-01, pp. : o306-o308

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Abstract

The title compound, a horminone derivative with the systematic name 7‐acetyl‐12‐methoxy­abieta‐8,12‐diene‐11,14‐dione, C23H32O5, was isolated from Hyptis verticillata from St. Mary, Jamaica. In the mol­ecule, there are three fused six‐membered rings, namely a substituted quinone ring in a slight boat conformation fused to a central acetyl‐ and methyl‐substituted cyclo­hexene ring in a half‐chair conformation, which is trans‐fused to a dimethyl‐substituted cyclo­hexane ring in a chair conformation. A single weak intra­molecular C—H⋯O hydrogen bond links mol­ecules into extended chains in the b axis direction.

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