Bis(μ‐3,5‐di‐2‐pyridyl‐1,2,4‐triazolato‐κ4N1,N5:N2,N3)bis[(methanol‐κO)(thiocyanato‐κN)iron(II)]

Publisher： John Wiley & Sons Inc

E-ISSN： 1600-5368|63|9|m2319-m2319

ISSN： 1600-5368

Source： Acta Crystallographica Section E, Vol.63, Iss.9, 2007-09, pp. : m2319-m2319

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Abstract

In the title centrosymmetric dinuclear iron(II) compound, [Fe2(C12H8N5)2(NCS)2(CH4O)2], the deprotonated 3,5‐di‐2‐pyridyl‐1,2,4‐triazole ligand uses a pair of Npyridyl/Ntriazolyl atoms to chelate one metal atom and the other pair of Npyridyl/Ntriazolyl atoms to chelate the other metal atom. Each Fe atom is octahedrally coordinated by four N atoms surrounding the metal center in a square‐planar environment. Above and below this plane are located the N atom of the thiocyanate anion and the O atom of the methanol molecule. Intermolecular O—H...N hydrogen bonding gives rise to a layer motif.

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