Publisher： John Wiley & Sons Inc
E-ISSN： 1600-5368|63|7|m1968-m1968
ISSN： 1600-5368
Source： Acta Crystallographica Section E, Vol.63, Iss.7, 2007-07, pp. : m1968-m1968
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Abstract
The title compound, (C15H13N3)4[ReBr6][ReBr4O(H2O)]2Br4·2H2O, is a mixed‐valence molecular salt containing rhenium(IV) (as centrosymmetric [ReBr6]2− anions) and rhenium(V) (as trans‐[ReO(H2O)Br4]− oxidoanions). The Re—O and Re—Br distances are consistent with the different oxidation states of Re in the anions. A complex hydrogen‐bonding network helps to establish the crystal packing.
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