Poly[tetra‐μ₂‐aqua‐diaqua‐μ₂‐chlorido‐di‐μ₂‐oxo‐dioxo[μ₇‐N,N,N′,N′‐(propane‐1,2‐diyldinitrilo)tetraacetato]dimolybdenum(V)trisodium(I)]

Publisher： John Wiley & Sons Inc

E-ISSN： 1600-5368|63|8|m2106-m2106

ISSN： 1600-5368

Source： Acta Crystallographica Section E, Vol.63, Iss.8, 2007-08, pp. : m2106-m2106

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Abstract

The title compound, [Na₃Mo₂(C₁₁H₁₄N₂O₈)ClO₄(H₂O)₆]_n, contains dioxo‐bridged Mo₂O₄ units. Each Mo^V atom has a distorted octahedral coordination geometry, and the two coordination octahedra share a common edge to form a dinuclear complex. The dinuclear complexes lie in layers, between which Na⁺ cations, Cl⁻ anions and water molecules form a complex network.

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