Aqua{4,4′‐dimethoxy‐2,2′‐[1,2‐phenylenebis(nitrilomethylidyne)]diphenolato‐κ4O,O′,N,N′}zinc(II)

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|63|6|m1633-m1634

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.63, Iss.6, 2007-06, pp. : m1633-m1634

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

In the title compound, [Zn(C22H18N2O4)(H2O)], the ZnII center, on a crystallographic mirror plane, is in a five‐coordinate N2O3 environment that is approximately square pyramidal, with the N2O2 tetradentate Schiff base ligand as the basal plane and the water molecule in the apical position. Intermolecular O—H...O and weak C—H...O interactions link the molecules into chains along [010]. These chains are further interconnected in a zigzag manner into a three‐dimensional network.