Di‐μ‐bromo‐bis­{aqua­[(5‐bromo‐1H‐imidazol‐4‐ylmethyl­ene)(2‐pyridylmeth­yl)amine‐κ3N,N′,N′′]nickel(II)} dibromide

Publisher： John Wiley & Sons Inc

E-ISSN： 1600-5368|62|10|m2464-m2466

ISSN： 1600-5368

Source： Acta Crystallographica Section E, Vol.62, Iss.10, 2006-10, pp. : m2464-m2466

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Abstract

In the title compound, [Ni2Br2(C10H9BrN4)2(H2O)2]Br2, the asymmetric unit consists of one half‐cation and one Br− anion. The dinuclear cation is located on an inversion centre and each NiII ion is chelated by one tridentate (5‐bromo‐1H‐imidazol‐4‐ylmethyl­ene)(2‐pyridylmeth­yl)amine (BIPI) ligand, one water mol­ecule and two bridging Br− ligands. The tridentate BIPI ligand is essentially planar. Hydrogen bonds involving the Br− anions stabilize the crystal structure.

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