Poly[(μ2‐N,N‐dimethylformamide‐κ2O:O)(μ4‐terephthalato‐κ4O:O′:O′′:O′′′)iron(II)]

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|63|10|m2534-m2534

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.63, Iss.10, 2007-10, pp. : m2534-m2534

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Abstract

In the crystal structure of the title compound, [Fe(C8H4O4)(C3H7NO)]n, the FeII atom and the terephthalate group occupy special positions of 2/m site symmetry. The FeII atom is octahedrally coordinated: two O atoms of two dimethylformamide molecules occupy the axial positions, and the equatorial sites are occupied by the carboxylate O atoms of four different terephthalate groups. The compound adopts a polymeric three‐dimensional framework structure. The C and N atoms of the dimethylformamide ligand are disordered equally over two sites each, with further disorder of the H atoms.