Tetrakis(pyridine‐κN)bis(thiocyanato‐κN)copper(II)

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|63|5|m1445-m1445

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.63, Iss.5, 2007-05, pp. : m1445-m1445

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Abstract

In the molecule of the title complex, [Cu(NCS)2(C5H5N)4], the CuII atom is bonded in a distorted octahedral arrangement to two N atoms of two SCN and four N atoms of four pyridine ligands. A crystallographic twofold rotation axis passes through the Cu atom, and the N and para‐C atoms of two trans pyridine rings. In the crystal structure, weak π–π stacking interactions cause the formation of a supramolecular network structure.