Poly[diaqua‐μ4‐benzene‐1,4‐dicarboxyl­ato‐di‐μ2‐benzene‐1,4‐dicarboxyl­ato‐bis­(N,N′‐dimethyl­formamide)digadolinium(III)]

Publisher： John Wiley & Sons Inc

E-ISSN： 1600-5368|62|7|m1600-m1602

ISSN： 1600-5368

Source： Acta Crystallographica Section E, Vol.62, Iss.7, 2006-07, pp. : m1600-m1602

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Abstract

In the title compound, [Gd2(C8H4O4)3(C3H7NO)2(H2O)2]n, the central GdIII atom is nine‐coordinated by seven O atoms from benzene‐1,4‐dicarboxyl­ate (1,4‐BDC) ligands, one dimethyl­formamide and one water mol­ecule in a distorted tricapped trigonal–prism coordination. The 1,4‐BDC ligands link the GdIII atoms, forming a three‐dimensional structure. All aromatic rings are located on centres of inversion. The water mol­ecule forms hydrogen bonds to carboxyl­ate groups.

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