Bis(1,4,7‐triaza­cyclo­nona­ne‐κ3N)manganese(II) di‐μ‐diselenido‐bis­[selenidoarsenate(III)]

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|63|2|m581-m583

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.63, Iss.2, 2007-02, pp. : m581-m583

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Abstract

The title compound, [Mn(C6H15N3)2][As2Se6], contains a sandwich‐like centrosymmetric complex cation with two tridentate 9‐aneN3 (1,4,7‐triaza­cyclo­nona­ne) ligands, which coordinate the MnII atom in an octa­hedral manner. AsSe3 pyramids are linked by two Se—Se bonds into the centrosymmetric chair‐shaped six‐membered ring of the [As2Se6]2− counter‐anions.