Publisher： John Wiley & Sons Inc
E-ISSN： 1600-5368|63|2|m576-m578
ISSN： 1600-5368
Source： Acta Crystallographica Section E, Vol.63, Iss.2, 2007-02, pp. : m576-m578
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Abstract
The title complex, [Ir(C17H13NOP)ClH(C17H14NOP)]·1.896CHCl3, contains hydride, chloride, 6‐diphenylphosphino‐2‐hydroxypyridine (pyphosH) and 6‐diphenylphosphino‐2‐pyridonate (pyphos) ligands coordinated to an IrIII metal centre to give a distorted octahedral coordination geometry. The two P and two N atoms of the pyphosH and pyphos ligands lie with a cis coordination in the equatorial plane. An intramolecular O—H⋯O hydrogen bond is observed between the pyphosH and pyphos ligands.
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