Publisher： John Wiley & Sons Inc
E-ISSN： 1600-5368|62|7|m1489-m1491
ISSN： 1600-5368
Source： Acta Crystallographica Section E, Vol.62, Iss.7, 2006-07, pp. : m1489-m1491
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Abstract
In the title compound, [MnCl2(C10H8N2)2]·SC(NH2)2, the MnII atom is coordinated by four N atoms from two 2,2′‐bipyridyl ligands and two Cl− anions, resulting in a distorted cis‐MnCl2N4 octahedral geometry. The complexes and thiourea molecules are connected by N—H⋯Cl and N—H⋯S hydrogen bonds, leading to one‐dimensional tapes which are further organized into a three‐dimensional structure through π–π, C—H⋯π and C—H⋯Cl interactions.
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