(Acetonitrile‐κN)dichlorobis­(η5‐penta­methyl­cyclo­penta­dien­yl)uranium(IV)

Publisher: John Wiley & Sons Inc

E-ISSN: 1600-5368|62|11|m2942-m2943

ISSN: 1600-5368

Source: Acta Crystallographica Section E, Vol.62, Iss.11, 2006-11, pp. : m2942-m2943

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Abstract

The title compound, [U(C10H15)2Cl2(C2H3N)], is a bent uranium(IV) metallocene, in contrast with the recently reported linear ones that can be obtained in acetonitrile with anions less strongly coordinating than chloride. The two chloride ions in the equatorial plane are located next to each other, with the acetonitrile ligand on one side.