Tris­(ethyl­enedi­amine‐κ2N,N′)­zinc(II) bis(1,2‐di­cyano­ethyl­enedi­thiol­ato‐κ2S,S′)­cuprate(II)

Publisher： John Wiley & Sons Inc

E-ISSN： 1600-5368|60|12|m1915-m1917

ISSN： 1600-5368

Source： Acta Crystallographica Section E, Vol.60, Iss.12, 2004-12, pp. : m1915-m1917

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Abstract

The title complex, [Zn(C2H8N2)3][Cu(C4N2S2)2], exists as discrete ions. The cation lies on a twofold rotation axis and the anion lies on an inversion centre. The [Zn(C2H8N2)3]2+ cation exhibits a distorted octahedral geometry. In the [Cu(C4N2S2)2]2− anion, the CuII atom is in a slightly distorted square‐planar environment. The crystal packing is stabilized by hydrogen bonds of the types N—H⋯N and N—H⋯S.

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