Initial Processes of Proton Transfer in Salicylideneaniline Studied by Time-Resolved Photoelectron Spectroscopy

Publisher: Edp Sciences

E-ISSN: 2100-014x|41|issue|02031-02031

ISSN: 2100-014x

Source: EPJ Web of Conference, Vol.41, Iss.issue, 2013-03, pp. : 02031-02031

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Abstract

Excited state intramolecular proton transfer (ESIPT) in salicylideneaniline (SA) and selected derivatives substituted in para-position of the anilino group has been investigated by femtosecond time-resolved photoelectron spectroscopy (TRPES) and time-dependent density functional theory (TDDFT). The planarity of the molecule was found to be a key parameter to describe ESIPT.