A 2D Cd(II) Coordination Polymer Constructed From 1,3-di(4-pyridyl)propane and 2,7-naphthalenedisulfonate

Author： Xiao Zizhong   Zhou Ming   Han Zhengbo  

Publisher： Taylor & Francis Ltd

E-ISSN： 1553-3182|45|5|748-752

ISSN： 1553-3174

Source： Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol.45, Iss.5, 2015-05, pp. : 748-752

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Abstract

A new coordination polymer [Cd(2,7-nds)(bpp)2]·2DMA·4H2O (1) (2,7-nds = 2,7-naphthalene disulfonic acid, bpp = 1,3-di(4-pyridyl)propane, DMA = N,N-Dimethylacetamide) has been synthesized by assembly of Cd(II) with 2,7-nds and bpp ligands and characterized by elemental analysis, IR, TGA, and single-crystal X-ray diffraction. The X-ray diffraction analysis reveals that 1 crystallizes in the monoclinic crystal system, space group C2. Topological analysis of 1 discloses an uninodal 4-connected net with the sql topology.

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