Publisher： John Wiley & Sons Inc
E-ISSN： 1099-0690|2015|22|4950-4955
ISSN： 1434-193x
Source： EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Vol.2015, Iss.22, 2015-08, pp. : 4950-4955
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Abstract
AbstractAn efficient method for the CF3‐carbenoid C–H functionalization of benzenes and indoles using readily available methyl 3,3,3‐trifluoro‐2‐diazopropionate as a cross‐coupling partner under chelation‐controlled RhIII catalysis has been developed. The reactions proceeded smoothly with high regioselectivity in a few hours and allowed the simultaneous introduction of CF3 and carboxylate functions into the 2‐position of directing‐group‐containing benzenes and indoles.
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