Solvent Molecule Controlled Zinc(II) Metal‐Organic Frameworks with Different Topology

Publisher: John Wiley & Sons Inc

E-ISSN: 1521-3749|641|14|2380-2383

ISSN: 0044-2313

Source: ZAAC-JOURNAL OF INORGANIC AND GENERAL CHEMISTRY (ELECTRONIC), Vol.641, Iss.14, 2015-11, pp. : 2380-2383

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

AbstractTwo zinc(II) coordination polymers, namely [Zn2(bptc)(DMF)2(H2O)]n (1) and [Zn(bptc)0.5(DMA)]n (2) (H4bptc = biphenyl‐3,3′,5,5′‐tetracarboxylic acid, DMF = N,N′‐dimethylformamide, DMA = N,N′‐dimethylacetamide), were obtained under solvothermal conditions by varying the reaction solvents. Single crystal X‐ray diffraction analyses revealed that compound 1 features a 3D PtS type framework based on dinuclear [Zn2O(COO)2] subunits and compound 2 features a 3D lvt type framework based on paddle‐wheel shaped [Zn2(COO)4] subunits. Moreover, the luminescent and thermal stabilities of these two compounds were investigated.

Related content