Publisher: John Wiley & Sons Inc
E-ISSN: 1521-3749|641|14|2380-2383
ISSN: 0044-2313
Source: ZAAC-JOURNAL OF INORGANIC AND GENERAL CHEMISTRY (ELECTRONIC), Vol.641, Iss.14, 2015-11, pp. : 2380-2383
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Abstract
AbstractTwo zinc(II) coordination polymers, namely [Zn2(bptc)(DMF)2(H2O)]n (1) and [Zn(bptc)0.5(DMA)]n (2) (H4bptc = biphenyl‐3,3′,5,5′‐tetracarboxylic acid, DMF = N,N′‐dimethylformamide, DMA = N,N′‐dimethylacetamide), were obtained under solvothermal conditions by varying the reaction solvents. Single crystal X‐ray diffraction analyses revealed that compound 1 features a 3D PtS type framework based on dinuclear [Zn2O(COO)2] subunits and compound 2 features a 3D lvt type framework based on paddle‐wheel shaped [Zn2(COO)4] subunits. Moreover, the luminescent and thermal stabilities of these two compounds were investigated.
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