Unusual photoanisotropic alignment in amorphous azobenzene polymers

Publisher: John Wiley & Sons Inc

E-ISSN: 1938-3657|23|5|214-217

ISSN: 1071-0922

Source: JOURNAL OF THE SOCIETY FOR INFORMATION DISPLAY, Vol.23, Iss.5, 2015-05, pp. : 214-217

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Abstract

AbstractIt is well known that irradiation of azobenzene polymer films between 490 and 530 nm results in alignment of molecules perpendicular to the polarization of the incident beam. I have recently found that irradiation of amorphous azobenzene polymers with linearly polarized light at wavelengths between 560 and 630 nm, where the absorption is minimal, results in a possible uniaxial hedgehog arrangement of the molecules. Experiments performed with a dye laser, which can be tuned continuously between 560 and 630 nm, are described. Not only azobenzene but also another photosensitive molecule, bacteriorhodopsin, seems to exhibit this behavior.