Publisher: John Wiley & Sons Inc
E-ISSN: 1615-4169|357|14‐15|3155-3161
ISSN: 1615-4150
Source: ADVANCED SYNTHESIS & CATALYSIS, Vol.357, Iss.14‐15, 2015-10, pp. : 3155-3161
Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.
Abstract
AbstractThe synthesis and characterization of abnormal N‐heterocyclic carbene, cyclic (alkyl)(amino)carbene, and mesoionic carbene copper(I) complexes are reported. These organometallic species are obtained via a versatile and inexpensive synthetic pathway using readily available reactants, namely copper oxide and iminium salts. The catalytic activity of this series of complexes was evaluated in the [3+2] cycloaddition of alkynes with azides (CuAAC). Outstanding catalytic properties were observed for the abnormal NHC‐ and triazolylidene‐based copper(I) complexes.
Related content
APPLIED ORGANOMETALLIC CHEMISTRY (ELECTRONIC), Vol. 32, Iss. 3, 2018-03 ,pp. :
Synthesis of Complexes with Abnormal “Protic” N‐Heterocyclic Carbenes
ANGEWANDTE CHEMIE INTERNATIONAL EDITION, Vol. 54, Iss. 46, 2015-11 ,pp. :
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (ELECTRONIC), Vol. 2018, Iss. 2, 2018-01 ,pp. :