Bowing to the Pressure of π⋅⋅⋅π Interactions: Bending of Phenyl Rings in a Palladium(II) Thioether Crown Complex

Publisher： John Wiley & Sons Inc

E-ISSN： 1521-3773|52|19|5093-5095

ISSN： 1433-7851

Source： ANGEWANDTE CHEMIE INTERNATIONAL EDITION, Vol.52, Iss.19, 2013-05, pp. : 5093-5095

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

Compression of a parallel four‐fold phenyl embrace involving two cations in [Pd([9]aneS3)(PPh3)2](PF6)2 ([9]aneS3=1,4,7‐trithiacyclononane) leads to π⋅⋅⋅π stacking interactions and concomitant pyramidalization at the ipso carbon atom of one of the phenyl rings. These pressure‐induced transformations have been rationalized by Hirshfeld surface analysis, density functional calculations and natural bond orbital analysis.

Related content

Bowing to the Pressure of π⋅⋅⋅π Interactions: Bending of Phenyl Rings in a Palladium(II) Thioether Crown Complex

By  

ANGEWANDTE CHEMIE, Vol. 125, Iss. 19, 2013-05 ,pp. : 5197-5199 (3)

John Wiley & Sons Inc

Access to resources Recommend Favorite

Crystal Structure of a Mixed-Ligand Cu(II) Complex Forming Supramolecular Assembly via an Extensive H-Bonding and Ring-Ring π-π Interactions

By Siddiqi Zafar  

Journal of Chemical Crystallography, Vol. 42, Iss. 10, 2012-10 ,pp. : 1042-1045 (4)

Springer Publishing Company

Access to resources Recommend Favorite

Zn(II) and Cd(II) Complexes Extended Structures Sustained by Hydrogen Bonding, π–π and C–H···π Interactions

By Wu Gang   Wang Xiao-Feng   Guo Li   Li Hui-Hui  

Journal of Chemical Crystallography, Vol. 41, Iss. 7, 2011-07 ,pp. : 1071-1076 (6)

Springer Publishing Company

Access to resources Recommend Favorite

Hydrogen Bond, π–π, and CH–π Interactions Governing the Supramolecular Assembly of Some Hydrazone Ligands and Their MnII Complexes – Structural and Theoretical Interpretation

By  

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (ELECTRONIC), Vol. 2015, Iss. 11, 2015-04 ,pp. : 1958-1972 (15)

John Wiley & Sons Inc

Access to resources Recommend Favorite

Supramolecular Assembly of Achiral Alkynylplatinum(II) Complexes and Carboxylic β‐1,3‐Glucan into Different Helical Handedness Stabilized by Pt⋅⋅⋅Pt and/or π–π Interactions

By  

CHEMISTRY - A EUROPEAN JOURNAL, Vol. 21, Iss. 14, 2015-03 ,pp. : 5447-5458 (12)

John Wiley & Sons Inc

Access to resources Recommend Favorite