Publisher： John Wiley & Sons Inc
E-ISSN： 1615-4169|357|11|2540-2546
ISSN： 1615-4150
Source： ADVANCED SYNTHESIS & CATALYSIS, Vol.357, Iss.11, 2015-08, pp. : 2540-2546
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Abstract
AbstractNew 3rd generation designer ansa‐ruthenium(II) complexes featuring N,C‐alkylene‐tethered N,N‐dialkylsulfamoyl‐DPEN/η6‐arene ligands, exhibited good catalytic performance in the asymmetric transfer hydrogenation (ATH) of various classes of (het)aryl ketones in formic acid/triethylamine mixture. In particular, benzo‐fused cyclic ketones furnished 98 to >99.9% ee using a low catalyst loading.
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