Oxygen vacancies influenced interfacial coupling effect in epitaxial Fe2.6V0.4O4/BiFeO3 multiferroic heterostructures

Author: Jin C.   Wang L. Y.   Zheng D. X.   Bai H. L.  

Publisher: Edp Sciences

E-ISSN: 1286-4854|110|4|47009-47009

ISSN: 0295-5075

Source: EPL (EUROPHYSICS LETTERS), Vol.110, Iss.4, 2015-06, pp. : 47009-47009

Disclaimer: Any content in publications that violate the sovereignty, the constitution or regulations of the PRC is not accepted or approved by CNPIEC.

Previous Menu Next

Abstract

Fully epitaxial Fe2.6V0.4O4(FVO)/BiFeO3(BFO) heterostructures were deposited on SrTiO3(001) substrates by magnetron sputtering. The microstructure of the heterostructures was studied using high-resolution transmission electron microscopy (HRTEM). In order to investigate the oxygen-vacancies–influenced interfacial coupling, the FVO layers were deposited on BFO films with various oxygen partial pressures. With the increase of oxygen vacancy contents, the exchange bias effects of the FVO/BFO heterostructures were significantly suppressed, showing weakened interfacial coupling. The possible mechanism is that the oxygen vacancies weaken the interface Fe3+(A)–O2−–Fe3+(BFO) bonds by decreasing the bond angle.