Cyclopentanone Derivatives from 5‐Hydroxymethylfurfural via 1‐Hydroxyhexane‐2,5‐dione as Intermediate

Publisher: John Wiley & Sons Inc

E-ISSN: 1864-564x|11|2|356-359

ISSN: 1864-5631

Source: CHEMSUSCHEM (ELECTRONIC) CHEMISTRY AND SUSTAINABILITY, ENERGY & MATERIALS, Vol.11, Iss.2, 2018-01, pp. : 356-359

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Abstract

AbstractAn efficient strategy for the conversion of biomass derived 5‐hydroxymethylfurfural (HMF) into 2‐hydroxy‐3‐methylcyclopent‐2‐enone (MCP) by an intramolecular aldol condensation of 1‐hydroxyhexane‐2,5‐dione (HHD) has been developed. Further transformations of MCP towards the diol, enol acetate, levulinic acid and N‐heterocyclic compounds are also reported.

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