

Author: Steinmetz Wayne Trevor William
Publisher: Taylor & Francis Ltd
ISSN: 1061-0278
Source: Supramolecular Chemistry, Vol.19, Iss.6, 2007-09, pp. : 399-402
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Abstract
A combination of NMR spectroscopy and molecular modelling yields the structure of the host-guest complex formed between sodium dodecyl sulfate and a cavitand. Nuclear Overhauser enhancements and ring-current shifts indicate that bound SDS adopts two conformations. Molecular modelling and an analysis of exchange-broadened NMR line shapes support the kinetic model for the binding.
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