Effect of boron in Ni3Al: structural-transformation induced ductilization

Author: Chowdhury S.G.  

Publisher: Taylor & Francis Ltd

ISSN: 1362-3036

Source: Philosophical Magazine Letters, Vol.74, Iss.5, 1996-11, pp. : 327-330

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Abstract

The Ni3Al (L12) intermetallic compound after boron doping becomes ductile. It is argued that grain-boundary segregation is not the only cause of the increase in ductility. It is pointed out that the L12 structure undergoes transformation to D022 during deformation, and during the deformation of this D022 structure the material fails. With the addition of boron, the stability of the L12 structure is enhanced with respect to D022 and slows the transformation rate. Therefore the nucleation and propagation of cracks become inhibited. Numerous experimental observations have been explained with the proposed mechanism.