Trends in Chemical Composition of Wet-only Precipitation at Rural French Monitoring Stations Over the 1990-2003 Period

Author： Sicard Pierre Coddeville Patrice Sauvage Stéphane Galloo Jean-Claude

ISSN： 1567-7230

Source： Water, Air and Soil Pollution: Focus, Vol.7, Iss.1-3, 2007-03, pp. : 49-58

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Abstract

The long-term monitoring of precipitation and its chemical composition are important for identifying trends in rain quality and for assessing the effectiveness of pollution control strategies. A statistical test has been used to the atmospheric concentrations measured in the French rural monitoring network (MERA) in order to bring out spatio-temporal trends in precipitation quality in France over the period 1990-2003. The non-parametric Mann-Kendall test which has been developed for detecting and estimating monotonic trends in the time series was used and applied in our study at annual values of wet-only precipitation concentrations. The emission data suggest that SO₂ and NO_x emissions decreased (−3.3 and −2.0% year⁻¹, respectively) contrary to NH₃ emissions that increased slightly (+0.2% year⁻¹) over the period 1990-2002 in France. On the national scale, the pH values have a significant decreasing trend of −0.025 ± 0.02 unit pH year⁻¹. and concentrations in precipitation have a significant decreasing trend, −3.0 ± 1.6 and −3.3 ± 0.6% year⁻¹, respectively, corresponding with the downward trends in SO₂ emissions in France (−3.3% year⁻¹). A good correlation (R ² = 0.84) between SO₂ emissions and concentrations was obtained. The decreasing trend of was more significant (−5.4 ± 5.2% year⁻¹) than that of (−1.3 ± 2.4% year⁻¹). Globally, the concentration of the major ions showed a clear downward trend including marine and alkaline ions. In addition, the relative contribution of HNO₃ to acidity precipitation increased by 51% over the studied period.